Answer:
option (A) is correct
When aldehyde or ketones react with hydroxylamine (NH2OH), then oximes are formed. Symmetrical ketones form a single oxime while asymmetrical ketones and aldehydes can form two isomeric oximes.
Complete step by step solution:
An oxime is a chemical compound belonging to the class of imines. General formulas of oximes are RR′C= NOH, where R is an alkyl group. If R’ is hydrogen, then oxime formed is aldoxime because an aldehyde reacted with hydroxylamine. If R’ is another organic group, then the oxime is ketoxime because a ketone group reacted with hydroxylamine.
Oximes are generally synthesized by the condensation reaction of aldehydes or ketones with hydroxylamine. This reaction of hydroxylamine with aldehydes/ketones is nucleophilic addition reaction followed by the elimination of a molecule of water. The reaction is reversible and is catalysed by acids. Oxime is a combination of the words oxygen and imine.
Now, the reaction of acetaldehyde that is, CH3CHO with hydroxylamine:
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Thus, the product ethanol oxime formed in the reaction has two isomeric forms. This is because the lone pair of nitrogen can occupy two positions in space as can be seen in the above chemical reaction. HCHO is a symmetrical aldehyde, so it will not form isomeric oxime and other options are also incorrect, that is they will not form isomeric oximes.
